A study of the influence of refractories’ structure on the thermomechanical properties of the lining of the equipment of tunnel kilns has been carried out. The lining of kiln trolleys is subjected to a mechanical stress distributed evenly over the entire area and the most dangerous to brittle materials, as well as to tensile thermal stresses. The magnitude of the tensile thermal stress depends on the material and the structure of the lining. The mechanisms of destruction of products made of fireclay and liquid concrete have been studied. Mineralogical and petrographic analysis of fireclay refractories have been used, as trolley lining has established metasomatic interaction of the lining with the vapor-gas component of the kiln, as well as with the metal of the trolleys. Monolithic products, made of low-cement concrete with corundum filler, are characterized by high strength and resistance to abrasion. The total value of compression and thermal expansion stresses for them is 3.08 MPa, which is half the value of those of fireclay. When conducting the research to optimize the composition of trolley lining, a technology for manufacturing two-layer concrete blocks, combining the advantages of compositions, based on corundum and fireclay, has been developed. The chemical and granulometric composition of fireclay-based concrete in the lower thermal insulation layer and electrocorundum-based concrete in the upper reinforcing layer were selected in such a way, as to ensure similar values of linear thermal expansion coefficients and prevent possible destruction along the boundary between the layers during the operation.