“…The fluorescence emission is thus characterized by a well-resolved vibrational fine structure, in marked contrast to the broad and featureless absorption. 3,10,11,14,16,18,25 Band A overlaps short axis-polarized absorbance B with a maximum close to 35700 cm −1 (280 nm). Several short axispolarized transitions are predicted in this region, e.g., 1 1 B 2 , 2 B 2 and 1 1 B 3 states of the D 2 rotamer, and 1 1 B u and 2 1 B u states of the C 2h rotamer, but they are all predicted to be very weak (Tables 1 and 2).…”