“…It is well known that presence of sp 1 hybridized carbon will reduce the film hardness because of its linear structure, compared to a film composed of sp 2 and sp 3 carbon based materials. Also it is reported in the literature that methane is better precursor for hard film coating compared to acetylene (Fedosenko et al, 2001). By considering all above stated facts (nature of the precursor, plasma conditions and film properties), the most probable reactions among others are calculated using the equation (19), from the known values of densities of argon, methane and electron, as well as rate constants of various processes determined from the plasma parameters and known in the literature (Alman et al, 2000;Baulch et al, 1994;Denysenko et al, 2004;Pitts et al, 1982;Shiu & Biondi, 1978;Sieck & Lias, 1976;Tsang & Hampson, 1986),…”