Abstract:The asymmetric unit of the title compound, [MnI(C24H16N6)(H2O)2]I·H2O, consists of a cationic MnII complex, an I− anion and a solvent water molecule. In the complex, the MnII ion is six-coordinated in a considerably distorted octahedral environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine (tppz) ligand, one I− anion and two O atoms of two water ligands. The dihedral angles between the pyridyl rings [maximum deviation = 0.034 (6) Å] and their carrier pyrazine ring [maximum d… Show more
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