Diastereoselective synthesis of a “chiral-at-Ru” secondary phosphine complex

Gibson, Gregory L.; Morrow, Krista M.E.; McDonald, Robert; Rosenberg, Lisa

doi:10.1016/j.ica.2010.12.058

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“…The precursor complex [RuCl(ind)(PPh 3 ) 2 ] has been used as a starting material for the syntheses of ruthenium complex through ligand‐substitution reactions by us13,15e,15f and others 22. Accordingly, when [RuCl(ind)(PPh 3 ) 2 ] was heated with 1.1 equiv.…”

Section: Resultsmentioning

confidence: 99%

Synthesis, Structural Characterization, and Catalytic Activity of Indenyl Tris(N‐pyrrolyl)phosphine Complexes of Ruthenium

et al. 2016

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The synthesis, characterization, and catalytic activity of new ruthenium complexes of the tris(N-pyrrolyl)phosphine ligand [P(pyr) 3 ] are described. The new ruthenium complexes [RuCl(ind)(PPh 3 ){P(pyr) 3 }] and [RuCl(ind){P(pyr) 3 } 2 ] (ind = indenyl, η 5 -C 9 H 7 -) were synthesized in 73 and 63 % isolated yields, respectively, by thermal ligand exchange of [RuCl(ind)(PPh 3 ) 2 ] with P(pyr) 3 . The electronic and steric properties of the new complexes were studied through analysis of the X-ray structures and cyclic voltammetry. The new complexes [RuCl(ind)(PPh 3 )-{P(pyr) 3 }] and [RuCl(ind){P(pyr) 3 } 2 ] and the known complex [RuCl(ind){(PPh 3 ) 2 }] differed only slightly in their steric proper-[a]

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Section: Resultsmentioning

confidence: 99%