Diethylenetriaminium(3+) hexachlorobismuthate(III)

Abstract

Key indicatorsSingle-crystal X-ray study T = 295 K Mean (C-C) = 0.010 Å R factor = 0.031 wR factor = 0.081 Data-to-parameter ratio = 25.6For details of how these key indicators were automatically derived from the article, see An ORTEPII plot (Johnson, 1976) of (I) with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level.

Bis(3-azaniumylpropyl)azanium hexachloridobismuthate(III) monohydrate

“…For related structures, see: Chaabouni et al (1998); Fu et al (2005); Rhandour et al (2011); Ouasri et al (2013). For bondvalence-sum calculations, see: Brown & Altermatt (1985).…”

“…This work is a part of our study on the crystal structure of alkylpolyammoniumbismuthate(III) chorides. This investigation was extended to aliphatic diamines of general formula NH 2 (CH 2 ) n NH 2 (Chaabouni et al, 1998;Rhandour et al, 2011;Ouasri et al, 2013) and triamines of general formula NH 2 (CH 2 ) n NH(CH 2 ) n NH 2 (Fu et al, 2005) in order to examine the effect of the flexible cation on the bismuth(III) coordination geometry. In these compounds the Bi atom shows a tendency toward distorted octahedral coordination with some rather long Bi-Cl bonds, which is attributed to the aspherical distribution of the lone pair electrons at Bi(III).…”

Bis[N-methylpiperidinium(2+)] di-μ-chloro-bis[tetrachlorobismuthate(III)] dihydrate

“…The preceding report (Fu et al, 2005) describes the isolation of diethylenetriammonium hexachlorobismuthate from the reaction of diethylenetriamine and bismuth trichloride. The use of the diamine N-methylpiperazine in place of the triamine yielded bis(N-methylpiperidinium) decachlorodibismuthate dihydrate, (I) ( Fig.…”