Structural characterization, vibrational studies and optical properties of a new luminescent organic-inorganic material [C6H20N3]BiI6·H2O

Novel zero-dimensional lead-free bismuth based perovskites: from synthesis to structural and optoelectronic characterization

“…The great amount of hydrogen bond donors avoids the iodide being shared, leading to a mononuclear bismuth complex, also observed for similar systems in the literature. [38][39][40][41] Although only one terpy unit is present in the asymmetric unit of this compound, half of them are doubly protonated (H 2 terpy 2+ ), and the other half singly protonated (Hterpy + ). In the difference Fourier map the second hydrogen atom was hardly found around the N1 or N3 atoms, suggesting that both can be protonated, and thus the occupancy of H1 and H3 was fixed as 0.25, for the sake of charge equilibrium.…”

Highly Emissive Self‐Trapped Excitons in Fully Inorganic Zero‐Dimensional Tin Halides

“…The library of 0D metal halides with octahedral building units includes both lead‐based and lead‐free compounds: Ti IV , Hf IV , Zr IV , Pd IV , Pb II , Sn IV , Te IV , Sb III , and Bi III . However, only several of these examples exhibit photoluminescence (PL) at room temperature (RT), and this emission is seldom characterized by a high PL quantum yield (QY).…”

Crystal structure, spectroscopic measurement, optical properties, thermal studies and biological activities of a new hybrid material containing iodide anions of bismuth(iii)

“…The broad one with a maximum at 556 nm (2.23 eV) and the weak one with a maximum at 588 nm (2.10 eV), located in the red region, indicate that this compound is a potential candidate for red photoluminescence materials. 75 These peaks are attributed to band to band and excitonic emissions within the iodobismuthate inorganic part, respectively. The luminescence originates from electronic transitions within the inorganic part [Bi 4 I 16 ] 4À .…”