A systematic alteration
in the optical properties of W:Al2O3 nanocomposite
films is demonstrated by precisely varying
the W cycle percentage (W%) from 0 to 100% in Al2O3 during atomic layer deposition. The direct and indirect band
energies of the nanocomposite materials decrease from 5.2 to 4.2 eV
and from 3.3 to 1.8 eV, respectively, by increasing the W% from 10
to 40. X-ray absorption spectroscopy reveals that, for W% < 50,
W is present in both metallic and suboxide states, whereas, for W%
≥ 50, only metallic W is seen. This transition from dielectric
to metallic character at W% ∼ 50 is accompanied by an increase
in the electrical and thermal conductivity and the disappearance of
a clear band gap in the absorption spectrum. The density of the films
increases monotonically from 3.1 g/cm3 for pure Al2O3 to 17.1 g/cm3 for pure W, whereas
the surface roughness is greatest for the W% = 50 films. The W:Al2O3 nanocomposite films are thermally stable and
show little change in optical properties upon annealing in air at
500 °C. These W:Al2O3 nanocomposite films
show promise as selective solar absorption coatings for concentrated
solar power applications.