It is the saturation of the transition temperature Tc in the range of 24 K
for known materials in the late sixties which triggered the search for
additional materials offering new coupling mechanisms leading in turn to higher
Tc's. As a result of this stimulation, superconductivity in organic matter was
discovered in tetramethyl-tetraselenafulvalene-hexafluorophosphate,
(TMTSF)2PF6, in 1979, in the laboratory founded at Orsay by Professor Friedel
and his colleagues in 1962. Although this conductor is a prototype example for
low-dimensional physics, we mostly focus in this article on the superconducting
phase of the ambient-pressure superconductor (TMTSF)2ClO4, in which the
superconducting phase has been studied most intensively among the TMTSF salts.
We shall present a series of experimental results supporting nodal d-wave
symmetry for the superconducting gap in these prototypical
quasi-one-dimensional conductors.Comment: Review article with 35 pages and 19 figures. Title, text, figures,
and references are modified. To be published in Compte Rendu de Physique.
Comments are welcom