Dimethyl Tartronate

Fisher, Harry J; Simons, H A B

doi:10.1021/ja01436a600

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Growth From Gels1

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“…This initial discovery stimulated a strong interest in understanding how the process worked. The idea for growing crystals in a gel media was stimulated by the research work of Fisher and Simons [183] in 1926. Early efforts on growing crystals in gels include the work of Hatschek [181] in 1911 and Dreaper [182] in 1913.…”

Section: Growth From Gelsmentioning

confidence: 99%

Crystal Growth through the Ages

Feigelson

2015

Handbook of Crystal Growth

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Section: Growth From Gelsmentioning

confidence: 99%

Crystal Growth through the Ages

Feigelson

2015

Handbook of Crystal Growth

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Rh^II‐Catalyzed Reactions of Diazocarbonyl Compounds with Dicarboximides

et al. 2006

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The reaction of RhII–oxocarbenoids derived from acyclic diazocarbonyl compounds with phthalimide and succinimide proceeds chemoselectively at the oxygen atom of the imidic carbonyl group, giving rise to the intermediate formation of carbonyl ylides. Intramolecular stabilization of these highly reactive species occurs in three different ways, and is controlled by the structure of the 2‐oxocarbenoids. Carbonyl ylides from diazo esters mainly experience a [1,4]‐hydrogen shift, and in this case, the corresponding O‐alkylimidates are formed as the final products. These ylides may also be stabilized by 1,3‐dipolar electrocyclization with intermediate formation of an oxirane. Carbonyl ylides with an acyl group in the carbene moiety undergo an intramolecular 1,5‐dipolar electrocyclization to produce 1,3‐dioxole derivatives. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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Dimethyl Tartronate

Cited by 2 publications

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Crystal Growth through the Ages

Crystal Growth through the Ages

Rh^II‐Catalyzed Reactions of Diazocarbonyl Compounds with Dicarboximides

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Dimethyl Tartronate

Cited by 2 publications

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Crystal Growth through the Ages

Crystal Growth through the Ages

RhII‐Catalyzed Reactions of Diazocarbonyl Compounds with Dicarboximides

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Rh^II‐Catalyzed Reactions of Diazocarbonyl Compounds with Dicarboximides