Functionalized TiO 2 nanotube arrays with decoration of MnO 2 nanoparticles (denoted as HTiO 2 /C/MnO 2 ) have been synthesized in the application of electrochemical capacitors. To improve both areal and gravimetric capacitance, hydrogen treatment and carbon coating process were conducted on TiO 2 nanotube arrays. By scanning electron microscopy and X-ray photoelectron spectroscopy, it is confirmed that the nanostructure is formed by the uniform incorporation of MnO 2 nanoparticles growing round the surface of the TiO 2 nanotube arrays. Impedance analysis proves that the enhanced capacitive is due to the decrease of charge transfer resistance and diffusion resistance. Electrochemical measurements performed on this H-TiO 2 /C/MnO 2 nanocomposite when used as an electrode material for an electrochemical pseudocapacitor presents quasi-rectangular shaped cyclic voltammetry curves up to 100 mV/s, with a large specific capacitance (SC) of 299.8 F g -1 at the current density of 0.5 A g -1 in 1 M Na 2 SO 4 electrolyte. More importantly, the electrode also exhibits long-term cycling stability, only *13 % of SC loss after 2000 continuous charge-discharge cycles. Based on the concept of integrating active materials on highly ordered nanostructure framework, this method can be widely applied to the synthesis of high-performance electrode materials for energy storage.