Alternatives for
the removal of 1,4-dioxane in the context of a
carbon-based advanced treatment were considered in this study. In
ozonation, monochloramine used for bromate control limited 1,4-dioxane
removal by scavenging hydroxyl radicals; however, most other ozone-reactive
trace contaminants were well removed. Hydrogen peroxide (H2O2) addition enhanced 1,4-dioxane removal but could not
control bromate formation when using a traditional ozone contactor,
and CT credit could not be achieved. UV advanced oxidation (UVAOP)
tests were conducted with H2O2 in the downstream
UV disinfection system. Up to 75% removal was achieved. Pilot experiments
showed that bromate could be controlled using multiple smaller ozone
doses with H2O2. Analyses of chemical and energy
costs were performed for the demonstration-scale and full-scale designs.
O3–H2O2 using the multipoint
dissolution approach of O3–H2O2 was significantly less expensive than UVAOP under most operating
conditions for similar levels of 1,4-dioxane removal and was the preferred
method for 1,4-dioxane removal. However, UVAOP was cost-competitive
with O3–H2O2 at low GAC effluent
TOC (≤2 mg/L) and if H2O2 was not quenched
with free chlorine, which was a major cost of UVAOP. Early GAC regeneration
to improve UVAOP performance was not cost-effective but may be necessitated
by other treatment objectives.