2016
DOI: 10.1016/j.tetlet.2016.04.108
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Direct synthesis of nitriles from cleavage of C C double bond with nitrite as the nitrogen source and oxidant

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Cited by 12 publications
(10 citation statements)
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“…The evolution of the ketoxime 6 to benzonitrile 3a would occur as previously reported,[9a] with the production of 1‐phenylglyoxal dioxime 7 ( path c ), which was detected as a reaction intermediate by GC‐MS, that in turn should give the benzonitrile 3a most probably through an abnormal Beckman rearrangement ( path d ) …”
Section: Resultssupporting
confidence: 67%
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“…The evolution of the ketoxime 6 to benzonitrile 3a would occur as previously reported,[9a] with the production of 1‐phenylglyoxal dioxime 7 ( path c ), which was detected as a reaction intermediate by GC‐MS, that in turn should give the benzonitrile 3a most probably through an abnormal Beckman rearrangement ( path d ) …”
Section: Resultssupporting
confidence: 67%
“…Reaction conditions were surveyed on styrene ( 1a ) as a model substrate, which was treated for 1 hour with 4 equivalents of sodium nitrite at 100 °C, under inert atmosphere, and without any other additive. [9a]…”
Section: Resultsmentioning
confidence: 99%
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