Polymer-derived
ceramic (PDC)-based high-temperature thin-film
sensors (HTTFSs) exhibit promising applications in the condition monitoring
of critical components in aerospace. However, fabricating PDC-based
HTTFS integrated with high-efficiency, high-temperature anti-oxidation,
and customized patterns remains challenging. In this work, we introduce
a rapid and flexible selecting laser pyrolysis combined with a direct
ink writing process to print double-layer high-temperature antioxidant
PDC composite thin-film thermistors under ambient conditions. The
sensitive layer (SL) was directly written on an insulating substrate
with excellent conductivity by laser-induced graphitization. Then,
the antioxidant layer (AOL) was written on the surface of the SL to
realize the integrated manufacturing of double-functional layers.
Through characterization analysis, it was shown that B2O3 and SiO2 glass phases generated by the PDC
composite AOL could effectively prevent oxygen intrusion. Therefore,
the fabricated PDC composite thermistors exhibited a negative temperature
coefficient in the temperature range from 100 to 1100 °C and
high repeatability below 800 °C. Meanwhile, it has excellent
high-temperature stability at 800 °C with a resistance change
of only 2.4% in 2 h. Furthermore, the high-temperature electrical
behavior of the thermistor was analyzed. The temperature dependence
of the conductivity for this thermistor has shown an agreement with
the Mott’s variable range hopping mechanism. Additionally,
the thermistor was fabricated on the surface of an aero-engine blade
to verify its feasibility below 800 °C, showing the great potential
of this work for state sensing on the surface of high-temperature
components, especially for customized requirements.