refractive, diffraction and optical fiber components. In particular, diffraction grating (DG) is one of the key elements for the design and creation of modern optoelectronic devices. One of the most prominent materials for the creation of DGs is liquid crystals. The main feature of these systems is that liquid crystals combine properties such as optical anisotropy inherent for crystals and molecular mobility. High sensitivity to an external field, in particular to an electric field, makes liquid crystals very useful for the creation of DGs with tunable properties. The combination of these properties enables easy control of optical characteristics of such systems and opens wide perspectives for the design of new materials for diffractive optics.Among the different types of liquid crystalline (LC) phases, cholesteric liquid crystal (CLC) phase possesses intrinsic periodicity in the form of the helical supramolecular structure (Figure 1). With the realization of definite alignment conditions, this periodicity has been exploited for generation of DGs. [8,9] Another remarkable feature of the cholesteric mesophase is selective light reflection with the reflection wavelength determined by the simple Equation (1) where n is the average refractive index, and P is the helix pitch. The specific value of helix pitch depends on the chemical structure of the molecules forming the cholesteric phase and concentration of chiral moieties. One of the easiest ways to obtain the cholesteric mesophase is by doping the nematic matrix with chiral components (Figure 1). Variation of structure of chiral molecules by external stimuli leading, for examples, to the photoisomerization, is effectively used for fine tuning of the helix pitch. [10][11][12][13][14][15][16][17] In addition, the application of an electric field also provides a convenient opportunity to change optical properties of the CLC phase. [18][19][20][21] These unique properties enable to design a great variety of optical elements and devices based on CLC layers, films, or cells. Among them it is necessary to mention the media for photo-optical data recording, [22][23][24][25] electrically switchable mirrors, [26,27] optically controllable linearpolarization rotators, [28] coatings with controllable friction and adhesion, [29] materials for display technology, [23,30] secure Modern optics and photonics constantly require break-through materials and designs in order to achieve miniature, lightweight, highly tunable, and effective optical devices. One of the basic optical components is the diffraction grating (DG), widely used for the dispersion of light, beam steering, etc. This review gathers research efforts on diffractive optical elements based on cholesteric liquid crystal (CLC) materials with a supramolecular helical architecture. All main types and fabrication approaches of periodic diffractive structures from CLCs are classified and described. Key optical properties of DGs, their advantages and drawbacks are considered. Special attention is paid on the tunability of DG...