Ti-rich garnet is found within calcitic ijolite from the Oka carbonatite complex in Canada, which is characterized by 58%-73% andradite component (2.12 wt.%-4.18 wt.% TiO 2 ) and classified as melanite. The garnet displays complex zoning and contains abundant high field strength elements (HFSEs) and rare earth elements (REEs). Three groups (I, II, III) have been identified based on their petrographic nature. Compared to groups II and III, Group I garnet cores contain higher TiO 2 , MgO, HFSE, and REE and lower SiO 2 abundances. The distinct chemical and petrographic signatures of the investigated garnets cannot be attributed to simple closed system crystallization, but they are consistent with the multi-pulse magma mixing. Combined with previously reported U-Pb ages for apatite from the calcitic ijolite, at least three stages of magma evolution and subsequent mixing have been involved in the generation of calcitic ijolite at Oka. The early-formed melt that generated Group I garnet core was later mixed with at least two small-volume, more evolved melts. The intermediate stage melt formed the remaining garnet along with some pyroxene, calcite, nepheline, and apatite at 127±3.6 Ma. The youngest, most evolved melt generated the majority of pyroxene, calcite, nepheline, and apatite within the calcitic ijolite at 115±3.1 Ma. KEY WORDS: melanite garnet, calcitic ijolite, Oka, magma mixing.
INTRODUCTIONThe Oka intrusive carbonatite complex (Fig. 1) comprises a broad spectrum of rocks, including carbonatite, okaite, ijolite, calcitic ijolite, jacupirangite, and alnöite. Previous chemical, isotopic, and geochronological investigations of the carbonatite and associated silicate rocks from Oka indicate the involvement of periodic generation of small volume, partial melts from a heterogeneous mantle plume and subsequent magma mixing Simonetti, 2014, 2013;Zurevinski and Mitchell, 2004). In addition, liquid immiscibility has been proposed for the formation of the carbonatite and associated silicate rocks at Oka (Treiman and Essene, 1985;Eby, 1975). Garnet dominated calcitic ijolite, which represents the most 'hybrid' carbonate-silicate suite of rocks at Oka, occurs solely proximal to the nature center (Fig. 1) and is the only rock type containing garnet within the complex.Titanium-rich garnets commonly consist of andradite melanite (Ca 3 Ti 2 [Al