The availability of high-resolution spaceborne synthetic aperture radar (SAR) data coupled with the ongoing refinement of tomographic SAR (TomoSAR) technology has made use of radar data feasible for preventive monitoring and assessment of built structures. In this study, we first applied extended differential TomoSAR (D-TomoSAR) to a set of 26 scenes of TerraSAR/TanDEM-X (TSX/TDX) (2013–2015) and 32 scenes of Cosmo-SkyMed (CSK) (2015–2017) images to estimate motions of skyscrapers, bridges and historical monuments in Nanjing City, China. The calculation and isolation of unknown parameters in the D-TomoSAR model, including linear velocity, thermal dynamics and structural heights, helped to estimate millimetric statistics of motion time series. Then, aforementioned two SAR datasets were tentatively tested using amplitude dispersion and phase stability indicators, highlighting the performance and sensitivity of X-band SAR in structural displacement monitoring. Experimental results demonstrated that motion indexes, e.g., heterogeneities of thermal amplitudes and spatiotemporal displacements, were useful to evaluate the conditions of built structures being monitored, in particular when their structural topology were visible owing to the enhanced density of persistent scatterer (PS) measurements. This study implies the value of high-resolution D-TomoSAR tools in the preventive monitoring and health diagnosis of built structures elsewhere over the world.