Low carbon technologies are necessary to address global warming issues through electricity decabonisation, but their large-scale integration challenges the stability and security of electricity supply. Energy storage can support this transition by bringing flexibility to the grid but since it represents high capital investments, the right choices must be made in terms of the technology and the location point in the network. Most of the potential for storage is achieved when connected further from the load, and Battery Energy Storage Systems (BESS) are a strong candidate for behind-the-meter integration. This work reviews and evaluates the state-of-the-art development of BESS, analysing the benefits and barriers to a wider range of applications in the domestic sector. Existing modelling tools that are key for a better assessment of the impacts of BESS to the grid are also reviewed. It is shown that the technology exists and has potential for including Electric Vehicle battery reuse, however it is still mostly applied to optimise domestic photovoltaic electricity utilisation. The barriers to a wider integration are financial, economic, technical, as well as market and regulation. Increased field trials and robust numerical modelling should be the next step to gain investment confidence and allow BESS to reach their potential.Energies 2019, 12, 3954 For this reason and due to economies of scale, the structure of the network was designed to have large centralised generators on one end of the network, enough aggregated loads on the other end, and a system of transmission and distribution of electricity in between, with higher voltages for long distances, and lower voltages closer to the loads for shorter sections of the grid. Therefore, the electricity generation fleet could be designed optimally and perform efficiently, as short term variations are small and predictable, relative to the overall production [8].In case of non-optimised and unsupervised penetration of renewable sources, problems such as mismatch between production and demand, voltage rise, or reverse power flows at transformers [8] are more likely to arise. Installing electricity storage-particularly on the low-voltage layers of the network [9]-could help reduce this problem by bridging the mismatch between demand and production.Storage may also play a role in addressing the evolution of the demand on the electricity network. The electrification of heat and transport sectors at different scales presents a potential for reducing Energies 2019, 12, 3954 3 of 27 GHG emissions as they are currently responsible for a substantial amount of pollutant emission [10], and draw the vast majority of their energy from the combustion of gas, oil and other fossil fuels [11]. However, shifting a significant part of the heat and transport demand to the electricity network is extremely challenging. The amount of energy it represents would generate a substantial stress on a network, which was not originally designed for it. Figure 2 gives an order of magnitude of the co...