“…Di(hetero)aryl disulfides are widely used as electrophiles instead of aryl halides for the construction of C‐S bond through S‐S bond cleavage,[8] because that disulfides are structurally symmetrical, air stable, and easy to handle [9]. Recently, we developed a series of method to construct C‐C, C‐N, and C‐S bonds through C‐S and S‐S bonds cleavage of di(hetero)aryl disulfides with various nucleophiles including aryl boronic acids, alkynes, Grignard reagents, and amines [10].…”