Nanobubbles (NBs) have a widespread application in antimicrobial
activity, wastewater treatment, and ecological restoration due to
numerous peculiar characteristics, such as small diameter, long-term
stability, and ability to produce hydroxyl radicals. Despite significant
applications, only limited comprehensive investigations are available
on the role of surfactants and pH in NBs characteristics. Therefore,
this study examines the effects of different surfactants (i.e., anionic,
cationic, and nonionic) and pH medium on bulk NB formation, diameter,
concentration, bubble size distribution (BSD), ζ-potential,
and stability. The effect of surfactant at concentrations above and
below the critical micelle concentration was investigated. NBs were
generated in deionized (DI) water using a piezoelectric transducer.
The stability of NBs was assessed by tracking the variation in diameter
and concentration over time. In a neutral medium, the diameter of
NBs is smaller than in other surfactant or pH mediums. The diameter,
concentration, BSD, and stability of NBs are strongly influenced by
the ζ-potential rather than the solution medium. BSD curve shifts
to a smaller bubble diameter when the magnitude of ζ-potential
is high in any solution. In pure water, surfactant, and pH mediums,
NBs have existed for a long time. NBs have a shorter life span in
environments with a pH ≤ 3. Surfactant adsorption on the surface
of NBs increases with increasing surfactant concentration up to a
certain limit, beyond which it declines substantially. The Derjaguin–Landau–Verwey–Overbeek
(DLVO) theory was used to interpret the NBs stability, resulting in
a total potential energy barrier that is positive and greater than
45.55 k
B
T for 6 ≤
pH ≤ 11, whereas for pH < 6, the potential energy barrier
essentially vanishes. Moreover, an effort has also been made to explicate
the plausible prospect of ion distribution and its alignment surrounding
NBs in cationic and anionic surfactants. This study will extend the
in-depth investigation of NBs for industrial applications involving
NBs.