Highlights
Nanobubble density during salting-out effect increases with salting-out parameter.
An ultrasound field with a high amplitude destroys the nanobubbles in salt solution.
R.I. of nanobubbles in NaCl and AlCl
3
were estimated to be 1.012 and 1.302, respectively.
The NBs during salting-out effect are observed to be stable only for up to three days.
We have investigated the origin,
stability, and nanobubble dynamics
under an oscillating pressure field followed by the salting-out effects.
The higher solubility ratio (salting-out parameter) of the dissolved
gases and pure solvent nucleates nanobubbles during the salting-out
effect, and the oscillating pressure field enhances the nanobubble
density further as solubility varies linearly with gas pressure by
Henry’s law. A novel method for refractive index estimation
is developed to differentiate nanobubbles and nanoparticles based
on the scattering intensity of light. The electromagnetic wave equations
have been numerically solved and compared with the Mie scattering
theory. The scattering cross-section of the nanobubbles was estimated
to be smaller than the nanoparticles. The DLVO potentials of the nanobubbles
predict the stable colloidal system. The zeta potential of nanobubbles
varied by generating nanobubbles in different salt solutions, and
it is characterized by particle tracking, dynamic light scattering,
and cryo-TEM. The size of nanobubbles in salt solutions was reported
to be higher than that in pure water. The novel mechanical stability
model is proposed by considering both ionic cloud and electrostatic
pressure at the charged interface. The ionic cloud pressure is derived
by electric flux balance, and it is found to be twice the electrostatic
pressure. The mechanical stability model for a single nanobubble predicts
the existence of stable nanobubbles in the stability map.
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