With the rapid development of 5th Generation Mobile Communication Technology (5G), late-model electromagnetic wave absorbing and shielding (EMAS) materials have proven to be the research emphasis of electromagnetic (EM) wave shelter. Great efforts have been made to optimize EMAS functional materials for diverse EM wavebands. [1] Each range of EM wave bands has a specific application in communication, electrical engineering, or information transmission. [2] For instance, ultrahigh frequency (UHF) EM wave of 0.3 < f < 3 GHz, also known as P/L/S or B/C/D/E band, is applied to television radar air navigation and mobile communication as well as microwave relay systems; the superhigh frequency (SHF) EM wave of 3 < f < 30 GHz, including S/C/X/Ku/K/ Ka-band or F/G/H/I/J/K band, is customarily adopted in digital telecommunication and satellite communication as well as waveguide communication. Moreover, EM waves in other frequency ranges, like terahertz wave and gamma ray, have been widely used in label-free DNA detection, high-temperature superconducting material research, radiographic testing, and even oncotherapy. In these cases, each specific application scenario requires specific EM waves in a specific frequency range, illustrating that EM wave clutters should be absorbed or otherwise shielded. Under these circumstances, developing novel and practical EMAS materials may meet the demands of EM wave science, especially in multifunctional fields.Traditional EMAS materials consist of resistance absorber, [3] dielectric absorber, [4] magnetic medium absorber, [5] and composites based on monomaterials as mentioned earlier, [6] including CuS, [7] MoSe 2 , [8] ferrites and alloys (Co x Fe 3Àx O 4 @C), [9] modified carbons (hollow carbon spheres), [10] etc. In the past decade, 2D transition metal carbides or nitrides, or MXenes, have been prefabricated and naturally applied to EMAS materials synthesis due to their outstanding EM wave loss capacity. [11] Many scholars have devoted themselves to MXene materials and structure design. The electrical conductivity of MXenes can reach 10 3 S cm À1 , leading to extraordinary EM wave shielding property. [12] Many reported MXene absorbers are monolayers, [13] whereas macrostructure design is introduced. Thus, macrodevices, like hollow MXene sphere foam, [14] are synthesized. It is