Dual-Emitting UiO-66(Zr&amp;Eu) Metal–Organic Framework Films for Ratiometric Temperature Sensing

Feng, Jifei; Liu, Tian‐Fu; Shi, Jianlin; Gao, Shuiying; Cao, Rong

doi:10.1021/acsami.8b04889

Cited by 84 publications

(58 citation statements)

References 70 publications

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“…[15] However,t he untilization of MOF-polymer hybrid materials as luminescent thermometer are really rare,e specially covalently tethering MOF into polymer chain with PSP strategy to realize temperature sensing in the form of flexible film has not been explored yet. [16] In this work, the mixed-lanthanide MOFs with polymerizable sites on the organic ligand were readily synthesized.…”

Section: Introductionmentioning

confidence: 99%

A Robust Mixed‐Lanthanide PolyMOF Membrane for Ratiometric Temperature Sensing

et al. 2020

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Temperature sensors play as ignificant role in biology,c hemistry,a nd engineering, especially those that can work accurately in anoninvasive manner.Weadopted aphotoinduced post-synthetic copolymerization strategy to realize amembranous ratiometric luminescent thermometer based on the emissions of two lanthanide ions.T his novel mixedlanthanide polyMOF membrane exhibits not only the integrity and temperature sensing behaviour of the Ln-MOF powder but also excellent mechanical properties,s uch as flexibility, elasticity,a nd processability.M oreover,t he polyMOF membrane shows remarkable stability under harsh conditions, including high humidity,s trong acid and alkali (pH 0-14), which allowed the mapping of temperature distributions in extreme circumstances.T his work highlights as imple strategy for polyMOF membrane formation and pushes forwardt he further practical application of Ln-MOF-based luminescent thermometers in various fields and conditions.

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Section: Introductionmentioning

confidence: 99%

A Robust Mixed‐Lanthanide PolyMOF Membrane for Ratiometric Temperature Sensing

et al. 2020

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“…Thus far, the UiO‐66 series has been incorporated into various matrixes bearing versatile characteristics for different purposes, and their incorporated mixed matrix membranes (MMM) and thin‐film nanocomposite (TFN) are famous functional materials that are applied in separation, adsorption, or dehydration in either gas or fluid phase, as well as in desalination, catalysis, sensing, and proton or ion transport in aqueous or other liquid phases. However, these types of composite membranes or films still encounter a set of problems and challenges to some extent, including uniform dispersion of MOFs, the compatibility and stability of matrix‐MOFs in the operating environment, the permeability or diffusivity of the flowing phase, the output efficacy compared to pristine MOFs, and so on.…”

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confidence: 99%

Super‐Stable, Highly Efficient, and Recyclable Fibrous Metal–Organic Framework Membranes for Precious Metal Recovery from Strong Acidic Solutions

Liu

Song

Liu

et al. 2019

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Precious metals such as palladium (Pd) and platinum (Pt) are marvelous materials in the fields of electronic and catalysis, but they are tapering day by day. Zr(IV)‐based metal–organic frameworks (MOFs) are competent for their recovery, notably in harsh environments, while the general powder form limits their practical application. Porous MOF‐based membranes with ultraefficient metal ion permeation, strong stability, and high selectivity are, therefore, strikingly preferred. Herein, a set of polymeric fibrous membranes incorporated with the UiO‐66 series are fabricated; their adsorption/desorption capabilities toward Pd(II) and Pt(IV) are evaluated from strongly acidic solutions; and the MOF–polymer compatibilities are investigated. Polyurethane (PU)/UiO‐66‐NH2 showed strong acid resistance and high chemical stability, which are attributable to strong π–π interactions between PU and MOF nanoparticles with a high configuration of energy. The as‐fabricated MOF membranes show extremely good adsorption/desorption performances without ruptures/coalitions of nanofibers or leak of MOF nanoparticles, and successfully display the efficacy in a gravity‐driven or even continuous‐flow system with good recycle performance and selectivity. The as‐fabricated MOF membranes set an example of potential MOF–polymer compatibility for practical applications.

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“…[ 25,26,32,45 ] For example, the emission is reported to be visualized from blue to orange/red within 50–135 °C for the liquid dihydrophenazine‐based thermometers, [ 32 ] from pale yellow/orange (room temperature) to orange (77 K) for [Cu(carbonyl‐thiophenolate)] n @PVDF films, [ 25 ] and from pink (237 K) to blue (337 K) for UiO‐66(Zr&Eu)@PVDF films. [ 46 ] More comparison with the reported organic and inorganic films has been listed in Table S5, Supporting Information.…”

Section: Resultsmentioning

confidence: 99%

Visualized Real‐Time and Spatial High‐Temperature Sensing in Air‐Stable Organic Films

Yao

Kong

Yan

et al. 2020

Adv Materials Technologies

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Temperature is a key parameter for both scientific and technological communities. [1-5] In particular, real-time and in situ spatial thermo-detection in a large area is essential and highly required in modern and intelligence industries. [4,6-10] Many types of thermometers utilize various temperature-dependent physical properties to detect environmental and physiological temperatures, such as volume, potential, and conductivity. [4] These sensors based on thermocouples and thermal resistance are commonly used due to their reliable performance and relatively low manufacturing costs; however, these traditional thermometers have difficulty in achieving large-area spatial temperature measurements, except when using costexpensive and complicated element array techniques. [11] Infrared thermometers based on blackbody radiation are easy to handle with thermal imaging but have the drawbacks of low spatial resolution, high noise, low image contrast, blurred visual effect, and a narrow grayscale. In recent years, luminescent thermometry has become increasingly appealing due to its non-invasive detection, fast response, high sensitivity, high spatial resolution, resistance to electrical/magnetic fields, and the ability to work with fast moving objects. [12-15] Luminescent thermometers are generally operated utilizing temperature-dependent photophysical parameters, such as emission lifetime, [16] emission intensity, [4] peak position, [17] and ratiometric emission intensities. [18] Among them, ratiometric thermometry, which is based on the temperature-dependent intensity ratios of two separate transitions, presents a more reliable and accurate measurement due to its self-referencing characteristics, i.e., independence on luminophore concentration, fluctuation of excitation source or detector, and luminescence background. [19,20] More importantly, this method is cost-effective and does not require expensive instruments as lifetime measurements. To date, most high-performance ratiometric luminescent thermometers applicable to wide-range and high-temperature sensing are generally based on inorganic metal-contained complexes, clusters, coordination polymers, and metal-organic frameworks. [18,21-24] However, these inorganic metal-based Large-area thin-film thermometers for high-temperature and wide-range gradient thermosensing and thermomapping are difficult to realize, although they are crucial for scientific and industrial applications. Most luminophores encounter significant emission quenching at heating, and among them, inorganic metal-based materials have difficulty forming uniform and large-areacompliant films. Herein, a series of heat-resistant blue luminophores based on carbazolyl-pyrene-substituted triarylphosphine oxides is developed. At a high temperature of 260 °C, their films still maintain high brightness (up to 79% of the original luminous intensity at-196 °C) due to the thermo-populating of the bright high-lying excited states. By hybridizing with a thermosensitive yellow chromophore presenting both excited state ...

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Dual-Emitting UiO-66(Zr&Eu) Metal–Organic Framework Films for Ratiometric Temperature Sensing

Cited by 84 publications

References 70 publications

A Robust Mixed‐Lanthanide PolyMOF Membrane for Ratiometric Temperature Sensing

A Robust Mixed‐Lanthanide PolyMOF Membrane for Ratiometric Temperature Sensing

Super‐Stable, Highly Efficient, and Recyclable Fibrous Metal–Organic Framework Membranes for Precious Metal Recovery from Strong Acidic Solutions

Visualized Real‐Time and Spatial High‐Temperature Sensing in Air‐Stable Organic Films

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