Nonvolatile memory (NVM) devices
were fabricated by implanting
a self-assembled monolayer (SAM) of functional dithienylethene (DTE)
derivative on the gold nanoparticle (Au-NP) surface in a pentacene-based
organic transistor. The Au-NPs and DTE served as a charge-trapping
medium and tunneling barrier layer, respectively. The transfer characteristic
of the NVM device showed a narrow hysteresis window and wide memory
window, indicating that the DTE-SAM served as a variable barrier layer
to regulate the trapping and detrapping of external free charges at
the Au-NPs. The energy gap introduced by the DTE-SAM is modulated
through photoisomerization between a ring-open form and a ring-closed
form by absorbing UV or visible light. For a memory device, the ring-closed
DTE allows more free charge injection into the trapping sites, and
the ring-open one better retains the trapped charges. A longer anchoring
alkanethiol chain at the DTE moiety can further extend the device’s
retention time. For the NVM operation, programming with the ring-closed
DTE and then switching the DTE structure to the ring-open form for
erasing can facilitate the charge trapping and charge retention with
the same molecule compared to operating all in the ring-open form
or all in the ring-closed form of DTE. The structural characterization
and electronic characteristics of these devices are discussed in detail.