Dual functionalized task specific ionic liquid promoted in situ generation of palladium nanoparticles in water: synergic catalytic system for Suzuki–Miyaura cross coupling

Abstract

A new task specific ionic liquid with hydroxyl and prolinate functionalities acts as a reducing agent and serves as a ligand and stabilizer for in situ formed palladium nanoparticles. This system displays high catalytic activity for Suzuki–Miyaura cross-coupling in water.

1-Butyl-3-methyl-2-(diphenylphosphino)imidazalolium hexafluorophosphate as an efficient ligand for recoverable palladium-catalyzed Suzuki-Miyaura reaction in neat water

“…In spite of abundant reports on performing the Suzuki-Miyaura coupling reactions, developments to improve it are currently done. For example, conducting the Suzuki-Miyaura coupling reaction in environmentally friendly solvents such as water have particular importance [24][25][26][27][28][29][30][31][32][33][34][35][36][37][38][39][40][41][42]. Water is a great alternative to organic solvents which disposal is a main problem in the industry.…”

Brønsted acidic ionic liquid-promoted direct C3-acylation of N-unsubstituted indoles with acid anhydrides under microwave irradiation

“…Thus, developing new catalysts for the synthesis of 3acylindoles with excellent yields and high selectivity under mild and environmentally friendly conditions is highly desirable. 18 Ionic liquids have received much attention in many elds including catalysis, [19][20][21][22][23][24][25] electrolytes, [26][27][28][29] extraction desulfurization, [30][31][32] biomass processing, [33][34][35] and biodiesel. [36][37][38][39] Friedel-Cras C3-acylation of indoles using ionic liquids has been reported in previous literature.…”

Highly efficient and recyclable water-soluble fullerene-supported PdCl2 nanocatalyst in Suzuki–Miyaura cross-coupling reaction

“…Compared to many of the mentioned catalysts, supported catalysts used in SuzukiMiyaura cross-coupling reaction with good coordination ability, easy synthesis, cost-effectiveness, and high thermal stability have become the core research focus of scientic researchers. [20][21][22][23][24][25] A number of studies have been reported for the immobilization of palladium nanocatalysts on support materials such as polyvinyl pyrrolidone 26 (PVP), amphiphilic resin,…”