Dual-wavelength light scattering for selective detection of volcanic ash particles

Abstract

Abstract. A new method is presented in this paper which analyses the scattered light of individual aerosol particles simultaneously at two different wavelengths in order to retrieve information on the particle type. We show that dust-like particles, such as volcanic ash, can be unambiguously discriminated from water droplets on a single particle level. As a future application of this method, the detection of volcanic ash particles should be possible in a humid atmosphere in the presence of cloud droplets. We show an example, how the characteristic behaviour of pure water's refractive index can be used to separate water droplets and dust-like particles which are commonly found in the micrometer size-range in the ambient air. The low real part of the water's refractive index around 2700–2800 nm results in low scattered light intensities compared to e.g. the visible wavelength range and this feature can be used for the particle identification. The two-wavelength measurement setup was theoretically and experimentally tested and studied. Theoretical calculations were done using Mie theory. Comparing the ratio of the scattered light at the two wavelengths (R value) for water droplets and different dust types (basalt, andesite, African mineral dust, sand, volcanic ash, pumice) showed at least 9 times higher values (on average 70 times) for water droplets than for the dust types at any diameter within the particle size range of 2–20 μm. The envisaged measurement setup was built up into a laboratory prototype and was tested with different types of aerosols. We generated aerosols from the following powders simulating dust-like particles: cement dust, ISO 12103-1 A1 Ultrafine Test Dust and Ash from the 2012 eruption of the Etna volcano. Our measurements verified the theoretical considerations, the median experimental R value is 8–21 times higher for water than for the "dust" particles.

A New Angular Light Scattering Measurement of Particulate Matter Mass Concentration for Homogeneous Spherical Particles

“…Under the high-temperature coal combustion condition, the coal-generated micron and submicron particles are mostly spherical given the mechanism of vaporization/condensation of the mineral elements in coal [24,26]. For many other particle measurement fields, particles, such as ash particles in fluidized bed furnace, sea-salt particles, soot aggregates, volcanic particles, and other dust particles in the atmosphere, exhibit an irregular shape [46,47,48,49], so the adaptability of this method to irregular particles should be taken into consideration. Recently, some research studies have assessed the scattering character of nonspherical particles with discrete dipole approximation (DDA) [50] and T-Matrix methods [51].…”