“…A mixture of impy (4) (6.0 g, 22.5 mmol), iridium(III) chloride hydrate (3.2 g, 10.7 mmol), 2-ethoxyethanol (60 mL), and water (20 mL) was deoxygenated and then heated to reflux under nitrogen for 24 h at 120 C. After cooling to room temperature, the mixture was filtrated and washed with ethanol to give product Ir(III)-m-chloride-bridged dimer (5). A mixture of the Ir(III)-mchloride-bridged dimer (5.80 g, 5.88 mmol), 2,2,6,6-tetramethyl-3,5-heptanedione (3.68 mL, 17.6 mmol), K 2 CO 3 (5.70 g, 41.24 mmol), and ethoxyethanol (40 mL) was deoxygenated and heated to reflux under nitrogen for 24 h at 120 C. After cooling to room temperature, the mixture was evaporated under vacuum and extracted with dichloromethane (100 mL).…”