Durch elektrisch geladene Ionophore induzierter Ionentransport in Modellmembranen mit Selektivität für Magnesium und Calcium

Erne, Daniel; Morf, Werner E.; Arvanitis, S.; Cimerman, Zvjezdana; Ammann, D.; Simon, W.

doi:10.1002/hlca.19790620410

Cited by 55 publications

(26 citation statements)

References 21 publications

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“…9 After Simon 10 published information about tridodecylamine ionophore for hydrogen sensing, we synthesized various types of tertiary amine compound ionophores, and strived to understand the response characteristics of these ionophores. [11][12][13][14][15] Particularly, after our result concerning SCE based on the tribenzylamine (TBA) ionophore 16 was published, which had a wider response range than the electrodes with tridodecylamine (TDDA) ionophore, many types of aromatic tertiary amine compound ionophores were synthesized and studied. [17][18][19][20][21] We found that the response ranges shifted to an alkali range (toward pH 14) by extending the chain length between the phenyl ring and nitrogen in the ionophores, and were able to synthesize ionophores that exhibited a linear response up to pH 14.…”

Section: Introductionmentioning

confidence: 99%

A Hydrogen Ion-Selective Poly(aniline) Solid Contact Electrode Based on Dibenzylpyrenemethylamine Ionophore for Highly Acidic Solutions

et al. 2004

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Ion-selective electrodes (ISEs) are chemical sensors with the longest history, and still probably have the largest number of applications. 1 More recently, two types of potentiometric wiretype electrodes (WTEs), such as coated wire electrodes (CWEs) 2 and solid contact electrodes (SCEs), 3,4 have exhibited rapid development. In WTEs, a total elimination of the internal filling solution provides new advantages. Simplicity of design, lower costs, mechanical flexibility, the possibility of miniaturization and microfabrication has widened the applications for WTEs in the fields of medicine and biotechnology. In SCEs of these two advanced types of WTEs, after polymerization, these polymer-coated metal electrodes were dipped into a PVC cocktail membrane solution until a bead was formed. Especially, these SCEs based on the electropolymerization method of amino derivatives onto the metal surface produced very good results, such as stabilization of the base potential, reproducibility, best selectivity, wide response ranges and fast response time. 5,6 Thus, in recent years, there have been many reports on hydrogen ion-selective SCEs 7 and hydrogen ion-selective ionophores. 8 We have studied hydrogen ion-selective ionophores and SCEs in our laboratory. 9After Simon 10 published information about tridodecylamine ionophore for hydrogen sensing, we synthesized various types of tertiary amine compound ionophores, and strived to understand the response characteristics of these ionophores. [11][12][13][14][15] Particularly, after our result concerning SCE based on the tribenzylamine (TBA) ionophore 16 was published, which had a wider response range than the electrodes with tridodecylamine (TDDA) ionophore, many types of aromatic tertiary amine compound ionophores were synthesized and studied. [17][18][19][20][21] We found that the response ranges shifted to an alkali range (toward pH 14) by extending the chain length between the phenyl ring and nitrogen in the ionophores, and were able to synthesize ionophores that exhibited a linear response up to pH 14. 22 As can be seen in the various results published until now on aromatic and aliphatic ionophores, however, there have been no reports on ionophores that are particularly effective in a strong acidic solution.In the present work, amine compound ionophores that could respond linearly to strong acid were synthesized, which has been noted as a limit of SPM (solvent polymeric membrane) ionophores, [13][14][15][16][17][18][19][20][21][22] and response characteristic due to structural changes of the ionophores in strong acid were demonstrated. Especially, we examined the responses resulting from increasing numbers of phenyl rings in ionophores, which had not been previously studied. Additionally, other common pH response characteristics of all solid-state potentiometric sensors for hydrogen ion based on poly(aniline), covered with a plastic PVC membrane and activated by these ionophores, are presented and evaluated in terms of analytical applications, such as in artificial serum an...

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Section: Introductionmentioning

confidence: 99%

A Hydrogen Ion-Selective Poly(aniline) Solid Contact Electrode Based on Dibenzylpyrenemethylamine Ionophore for Highly Acidic Solutions

et al. 2004

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“…2 Simon et al developed different PVC membrane pH electrodes based upon tri-n-dodecylamine, which gave good response characteristics. [3][4][5][6][7][8] Wu and Yu prepared a pH-sensitive electrode using methyldioctadecylamine (MDODA) as a neutral carrier.9 Later, some authors continued similar research, and other compounds have been investigated as ionophores for hydrogen ions, many of which can be used for a very wide range of pH values. [10][11][12][13][14][15][16][17][18][19][20][21][22][23] Calixarenes are metacylclophanes comprising phenolic and methylene units.…”

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confidence: 99%

Hydrogen Ion-Selective Poly(vinyl chloride) Membrane Electrode Based on a Calix[4]arene

et al. 2003

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IntroductionFor more than 60 years, pH-glass electrodes have been widely used, and pH measurements in various samples are still made using these electrodes. They are very popular due to their high selectivity and dynamic pH range. However, in spite of the distinctive potential characteristic of pH-glass electrodes and their use in routine pH measurements for so many years, they have certain limitations, such as high resistance, brittleness, instability in hydrofluoric acid and fluoride-containing media. They also create problems in the construction of microelectrodes for biological applications and in vivo measurements. That is why studies related to the construction of nonglass pH electrodes have been gaining momentum. The construction of PVC pH electrodes based on neutral carriers will solve most of these problems. The facts that PVC electrodes have low electrical resistance and that they are easy to construct have increased interest in the implementation of these electrodes in place of glass membranes. These electrodes are of great practical importance, since they are solid and unbreakable. For example, there have been numerous studies about the use of pH-sensitive liquid membrane electrodes in clinical studies. 1 Le Blanc et al. prepared a liquid-membrane electrode with p-octadecyloxy-m-chlorophenylhydrazonemesoxalonitrile (OCPH) as a proton carrier. 2 Simon et al. developed different PVC membrane pH electrodes based upon tri-n-dodecylamine, which gave good response characteristics. [3][4][5][6][7][8] Wu and Yu prepared a pH-sensitive electrode using methyldioctadecylamine (MDODA) as a neutral carrier.9 Later, some authors continued similar research, and other compounds have been investigated as ionophores for hydrogen ions, many of which can be used for a very wide range of pH values. [10][11][12][13][14][15][16][17][18][19][20][21][22][23] Calixarenes are metacylclophanes comprising phenolic and methylene units. They are very popular as attractive and excellent ionophores because they provide a platform for the attachment of convergent binding groups to create host molecules, mainly for the attraction of simple cations, anions and small molecules. [24][25][26][27][28][29][30][31] McKervey et al. first recognized that calixarenes with cations-complexing groups attached to the lower rim may possess the molecular requirements for the type of ionophore used in ion-selective electrodes (ISEs). 32,33 For example, the tetraesters of calix[4]arenes have been proved to be excellent ionophores for sodium in liquid membrane and PVC membrane electrodes. These types of electrodes based on such compounds were shown to be capable of measuring sodium in blood. 34,35 Some calixarenetetraesters are now commonly used in commercial blood electrolyte analyzers for sodium determination. The purpose of this study was to develop a hydrogen ionselective electrode using a macrocyclic compound of calix[4]arene as a neutral carrier and to determine its lifetime, response time, optimum working range and other response characteristics....

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“…7 predicts transport up to diffusion equilibrium where it finally holds that However, this equilibration transport proceeds with the maximum rate only as long as (8) …”

Section: )mentioning

confidence: 98%

“…5 and 6 apply, is the mediated transport of ions of a given charge z (cations or anions) across membranes that contain electrically charged carriers 171 [8] or combinations of charged and neutral carriers [9]. In this case, the presence of at least two permeating substrates N, namely the ions I' and J', is required for inducing a transport at zero current.…”

Section: )mentioning

confidence: 99%

Selective Transport Membranes and their Applicability for Novel Sensors

Morf¹,

Huser²,

Lindemann³

et al. 1986

Helvetica Chimica Acta

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Selective transport of given substrates through artificial membranes can be achieved by incorporation of electrically neutral or charged carriers. Such mediated transport described for alkali and alkaline-earth metal cations is reported here for the first time for certain anions using cobyrinate-type ionophores, and it is also conceivable to be realized for nonionic substrates (e. g. glucose). The fundamental requirements for corresponding co-transport and counter-transport membrane systems are set forth in view of a design of novel substrate-selective sensors for analytical-chemical applications.

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Durch elektrisch geladene Ionophore induzierter Ionentransport in Modellmembranen mit Selektivität für Magnesium und Calcium

Cited by 55 publications

References 21 publications

A Hydrogen Ion-Selective Poly(aniline) Solid Contact Electrode Based on Dibenzylpyrenemethylamine Ionophore for Highly Acidic Solutions

A Hydrogen Ion-Selective Poly(aniline) Solid Contact Electrode Based on Dibenzylpyrenemethylamine Ionophore for Highly Acidic Solutions

Hydrogen Ion-Selective Poly(vinyl chloride) Membrane Electrode Based on a Calix[4]arene

Selective Transport Membranes and their Applicability for Novel Sensors

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