21The Whalesback Cu-rich VMS deposit in the Newfoundland Appalachians is a 22 highly deformed deposit found on a steep limb of a closed and boudinaged overturned 23 fold. The deposit was intensely deformed at low temperature but medium pressure (>175 24 MPa) during the accretion of the composite Lushs Bight Oceanic Tract-Dashwoods 25 terrane onto the Humber margin at ca. 480 Ma. 26The ore mineralogy consists of chalcopyrite, pyrrhotite and pyrite with lesser 27 sphalerite and trace Ag-, Bi-and Hg-tellurides. Four styles of sulfide mineralization are 28 present: 1) disseminated (5%); 2) vein (50%); 3) breccia (25%); and 4) semi-massive to 29 massive (20%). Independent of mineralization style, massive pyrite and pyrrhotite (and 30 some chalcopyrite) are commonly parallel to main S 2 schistosity in the deposit, whereas 31 late chalcopyrite piercement veins occur at a high angle to S 2 . The progressive increase in 32 pressure and temperature produced a remobilization sequence wherein sphalerite was the 33 first sulfide phase to cross the brittle-ductile boundary, followed by pyrrhotite and finally 34 chalcopyrite. Maximum temperature was not high enough for the pyrite to cross the 35 brittle-ductile boundary. Instead, pyrite grains were incorporated and transported by 36 pyrrhotite and chalcopyrite during the ductile remobilization events, rounding and 37 fracturing them. Remobilization of the sulfides occurred mainly by plastic flow, but some 38 solution transport and re-precipitation is locally observed. 39In situ secondary ion mass spectrometry (SIMS) sulfur isotopes geochemistry of 40 sulfides yielded values of δ 34 S ranging from +2.7‰ to 4.7‰ for pyrite, +2.1‰ to 4.0‰ 41 for pyrrhotite and +1.3‰ to 4.7‰ for chalcopyrite. Sulfur isotopic modeling suggests 42 3 that at least 60% of the sulfur was derived from leaching of igneous rocks (i.e., basalts), 43 with the reminder derived from thermochemical sulfate reduction (TSR) of seawater 44 sulfate during alteration of the basalts by seawater. At the deposit scale, sulfur isotopes 45 retained their original signature and did not re-equilibrate during the secondary 46 deformation and remobilization events. 47