“…Rolled‐up nanotechnology offers an advanced strategy to deterministically rearrange two‐dimensional nanomembranes into three‐dimensional micro‐/nanohierarchical tubes, helices, rings, wrinkles and other advanced architectures for micro‐/nanooptics, biology, and electronics as well as energy storage applications . In our group, we have reported on various materials with rolled‐up tubular structures for advanced LIB anodes, such as RuO 2 ,[14a] Ge/Ti,[14b] Si/C,[14c] GeO 2 ,[14d] SnO 2 /Cu,[14f] and SiO x /SiO y , all of which have shown enhanced performance (e.g., capacity and cycling stability) due to the fast ionic transport and powerful strain accommodation benefited from the unique hollow micro‐/nanohierarchical structure.…”