Cement-based battery is a new area of research that is gaining popularity with the evolving idea of developing multifunctional and smart building solutions. This is deemed as a concept stirring revolution, because of the ability of the buildings to store energy and then power certain electronic applications. The core principle behind the development of cement-based batteries is the characteristics of the cement electrolyte acting as ionic conductor thereby facilitating the migration of ions between the electrodes. This review paper presents a compilation of works carried out by various researchers working towards the development of cement-based batteries along with a review on the various performance assessment parameters used by the authors, related to cement-based battery systems. In addition to the earlier works, the scope for future works in the development of cement-based batteries and the current work in progress from the authors’ front are reported as well.