We experimentally study two quantum phase transitions in a sodium spinor condensate immersed in a microwave dressing field. We also demonstrate that many previously unexplored regions in the phase diagram of spinor condensates can be investigated by adiabatically tuning the microwave field across one of the two quantum phase transitions. This method overcomes two major experimental challenges associated with some widely used methods, and is applicable to other atomic species. Agreements between our data and the mean-field theory for spinor Bose gases are also discussed.PACS numbers: 67.85. Hj, 03.75.Mn, 67.85.Fg, 03.75.Kk A spinor Bose-Einstein condensate (BEC) is a multicomponent BEC with an additional spin degree of freedom, which has provided exciting opportunities to study quantum magnetism, superfluidity, strong correlations, spin-squeezing, and massive entanglement [1][2][3][4][5]. The interesting interactions in spinor BECs are interconversions among multiple spin states and magnetic field interactions (or microwave dressing field interactions) characterized by q net , the net quadratic Zeeman energy. The interplay of these interactions leads to oscillations among multiple spin populations, which has been experimentally confirmed in F =123 Na spinor BECs [6][7][8][9][10][11][12], and in both F =1 and F =287 Rb spinor condensates [13][14][15][16][17].Several groups demonstrated the mean-field (MF) ground states of spinor BECs by holding BECs in a fixed magnetic field and letting spin population oscillations damp out over a few seconds [8][9][10][11]. The required damping time, determined by energy dissipation, may in some cases exceed the BEC lifetime. The exact mechanism involved in energy dissipation requires further study, although it has been shown that energy dissipates much faster in high magnetic fields [10]. For F =1 BECs, a magnetic field introduces only a positive q net , while a microwave field has a distinct advantage since it can induce both positive and negative q net [1,7,12,18,19]. As shown in Ref. [12], the same physics model explains spin-mixing dynamics observed in both microwave fields and magnetic fields. One would assume that, if given a long enough exposure to a microwave field, a spinor BEC could also reach its MF ground states. However, experimental studies on ground states of spinor BECs in microwave fields have proven to be very difficult, since these fields are created by near-resonant microwave pulses. Two major experimental challenges associated with microwave fields are atom losses and variations in magnetization m. Microwave-induced changes in both m and the atom number N can be detrimental, especially when a spinor BEC is exposed to a large microwave field for a prolonged time [7,12]. As a result, the phase diagram of F =1 BECs has not been well explored in the q net ≤ 0 region, where applying microwave fields may be necessary.In this paper, we demonstrate a new method to overcome the aforementioned experimental challenges and report the observation of two quantum phase ...