Molecular plasmonics, the area which deals with the interactions
between surface plasmons and molecules, has received enormous interest
in fundamental research and found numerous technological applications.
Plasmonic metamaterials, which offer rich opportunities to control
the light intensity, field polarization, and local density of electromagnetic
states on subwavelength scales, provide a versatile platform to enhance
and tune light-molecule interactions. A variety of applications, including
spontaneous emission enhancement, optical modulation, optical sensing,
and photoactuated nanochemistry, have been reported by exploiting
molecular interactions with plasmonic metamaterials. In this paper,
we provide a comprehensive overview of the developments of molecular
plasmonics with metamaterials. After a brief introduction to the optical
properties of plasmonic metamaterials and relevant fabrication approaches,
we discuss light-molecule interactions in plasmonic metamaterials
in both weak and strong coupling regimes. We then highlight the exploitation
of molecules in metamaterials for applications ranging from emission
control and optical modulation to optical sensing. The role of hot
carriers generated in metamaterials for nanochemistry is also discussed.
Perspectives on the future development of molecular plasmonics with
metamaterials conclude the review. The use of molecules in combination
with designer metamaterials provides a rich playground both to actively
control metamaterials using molecular interactions and, in turn, to
use metamaterials to control molecular processes.