“…It has been argued that the relevant spatial scale for hydrological state and flux heterogeneity is on the order of 100 m (Wood et al, 2011), while for biogeochemical dynamics it may be as small as 1 m (Burt and Pinay, 2005;Groffman et al, 2009;Frei et al, 2012;McClain et al, 2003). The current suite of land models representing coupled hydrological and biogeochemical cycles and used for analyses of water resources and water quality (e.g., HydroGeoSphere (Li et al, 2008(Li et al, ),al., 2006, MIKE-SHE (McMichael et al, 2006), WEP-L (Jia et al, 2006), and PAWS (Shen, 2009;Shen and Phanikumar, 2010)), as well as regional (e.g., Subin et al, 2011) and global (e.g., Koven et al, 2013;Tang et al, 2013) climate prediction are typically applied at resolutions that are orders of magnitude larger than these scales. Unfortunately, there are few large-scale observational datasets with which to test the impact of the discrepancies in scale between model representation and known variability of coupled hydrological and biogeochemical processes.…”