Effect of A-site modification on electrical properties and chemical stability of Ba1-Ca Ce0.5Zr0.3Y0.2O3-δ proton-conducting electrolyte

Zhou, Gaopeng; Liu, Ying; Luo, Yadan; Huang, Wenlong; Li, Bo

doi:10.1016/j.ceramint.2022.11.317

Ceramics International

2023

DOI: 10.1016/j.ceramint.2022.11.317

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Effect of A-site modification on electrical properties and chemical stability of Ba1-Ca Ce0.5Zr0.3Y0.2O3-δ proton-conducting electrolyte

Gaopeng Zhou

Ying Liu

Yadan Luo

et al.

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Cited by 13 publications

References 48 publications

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Recent Advances and Challenges in Perovskite‐Based Protonic Ceramic Electrolytes: Design Strategies and Fabrication Innovations

Nie,

Liu,

Xiao

et al. 2024

Adv Funct Materials

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Protonic ceramic electrochemical cells (PCECs) have received extensive research attention as full solid‐state, electrochemical devices that can interconvert electrical and chemical energies via rapid proton conduction at reduced temperatures. Nonetheless, the practical application of PCECs still faces numerous challenges. In addition to the development of electrode materials, the protonic ceramic electrolytes (PCEs), which are crucial for the performance and stability of PCECs, encounter issues such as poor sinterability, low ionic conductivity, and inadequate thermochemical matching. To address these obstacles, the design and optimization of protonic ceramic electrolytes have recently become essential research focuses in the field of PCECs. To achieve effective customization of the elemental composition, crystal structure, defect structure, ionic conductivity, and chemical stability, many candidates for electrolyte materials with various compositions have been proposed. This review also covers state‐of‐the‐art developments in PCE fabrication technologies, including powder synthesis, thin‐film deposition, more controllable sintering processes and interface treatments for structural integrity and ionic conductivity. This review comprehensively summarizes the most recent design approaches and optimization strategies for perovskite‐based protonic ceramic electrolyte materials and is crucial for advancing the commercialization of PCECs.

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Recent Advances and Challenges in Perovskite‐Based Protonic Ceramic Electrolytes: Design Strategies and Fabrication Innovations

Nie,

Liu,

Xiao

et al. 2024

Adv Funct Materials

View full text Add to dashboard Cite

show abstract

Effect of synthesis on structural, vibrational, and electrical properties of Ba1−xCaxCe0.8Nd0.2O3−δ (BCCN, 0 ≤ x ≤ 0.01) synthesized by sol–gel auto combustion method

Kothandan,

Prasad,

Shanmukhi

et al. 2024

Appl. Phys. A

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Preparation and performance study of Ba(1-x)SrxCe0.9Y0.1O3-δ (x = 0–0.5) proton conducting electrolytes

Yu,

Li,

Cai

et al. 2024

Ionics

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Effect of A-site modification on electrical properties and chemical stability of Ba1-Ca Ce0.5Zr0.3Y0.2O3-δ proton-conducting electrolyte

Cited by 13 publications

References 48 publications

Recent Advances and Challenges in Perovskite‐Based Protonic Ceramic Electrolytes: Design Strategies and Fabrication Innovations

Recent Advances and Challenges in Perovskite‐Based Protonic Ceramic Electrolytes: Design Strategies and Fabrication Innovations

Effect of synthesis on structural, vibrational, and electrical properties of Ba1−xCaxCe0.8Nd0.2O3−δ (BCCN, 0 ≤ x ≤ 0.01) synthesized by sol–gel auto combustion method

Preparation and performance study of Ba(1-x)SrxCe0.9Y0.1O3-δ (x = 0–0.5) proton conducting electrolytes

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