We investigated changes
in the optical
properties of indium tin oxide (ITO) nanocrystals as a function of
temperature. ITO is a plasmonic, wide-band-gap semiconductor capable
of absorbing UV and IR radiation. The nanoparticles were made using
a standard two-pot synthesis, which resulted in the formation of ITO
nanoparticles with myristic acid and oleylamine as surface passivation
ligands. Ligand exchange with (6–7% aminopropylmethylsiloxane)–dimethylsiloxane
copolymer allowed dispersion of the particles into a thermal fluid,
Duratherm S, which is capable of withstanding working temperatures
of 300 °C. Nanoparticles suspended in the fluid were heated over
a range of temperatures, and their properties were investigated using
IR spectrometry, UV–vis, transmission electron microscopy,
and particle size analysis. Although heating showed no change in particle
size, spectral changes were clearly observed in the form of a strong
blue shift and increased absorbance. These temperature-dependent changes
in the spectral properties of ITO were attributed to various factors
such as: (i) distribution of tin dopant throughout the nanocrystal
to increase the carrier concentration, (ii) removal of interstitial
oxygen to reduce electron scavenging, (iii) increased order in the
In2O3 structure to enhance carrier mobility,
and (iv) reduction in electron traps of tin–oxygen complexes.