Optoelectronic
properties of nonpolar a-plane
GaN are superior along the [0002] azimuth direction compared to other
azimuth directions. We have grown a-GaN on r-sapphire, and interdigitated electrode patterns of Au
were fabricated to restrict the carrier transport only along [0002]
azimuth. Surprisingly, the Schottky barriers of Au/GaN were found
to be asymmetric in nature as the current on the positive side was
different than negative for the same bias. Polarization on the boundaries
of the basal plane defects has been already investigated for the possible
reason of the Schottky barrier inhomogeneity. Thus, it can be expected
that the overall effect of these polarization centers would change
the Schottky barrier height of one of the electrodes. Electronic band-alignment
based on asymmetrical contacts reveals that the difference in the
Schottky barrier height would create a net electrical field toward
the higher Schottky barrier, which is exploited here for self-powered
photodetection and also enhanced photodetection at higher applied
bias. The spectral response of all the devices was studied within
300–700 nm, and it was found that spectral response enhances
with the applied voltage. The maximum responsivity and detectivity
for a 364 nm light source observed at 5 V was around 400 A W–1 and 6.6 × 1012 jones, while at 0 V, it was 4.67
mA W–1 and 3.0 × 1013 jones, respectively,
which is the highest known responsivity for a-plane
GaN to the best of our knowledge. The spectral response shows that
the devices work for a very narrow band of radiation and hence can
be used for selective UV-A photodetection. Overall, these results
demonstrate much-improved UV photodetection properties compared to
existing GaN-based photodetectors.