Effect of boron addition on formation of a fine-grained microstructure in commercially pure titanium processed by hot compression

Imayev, V. M.; Gaisin, Ramil; Imayev, R. M.

doi:10.1016/j.msea.2015.05.082

Cited by 17 publications

(4 citation statements)

References 18 publications

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“…A mean grain size decreased more than three times. The grain refinement effect of 0.02-0.2% boron is well known for unalloyed Ti [41], several Ti-based alloys [16,42], and Ti-Ni [43,44] and Ti-Al [45][46][47] intermetallic alloys. The difference in the grain size between 0.1 and 0.4 wt.% B was insignificant.…”

Section: Discussionmentioning

confidence: 99%

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Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Postnikova¹,

Котов²,

Базлов³

et al. 2023

Preprint

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The microstructure evolution, superplasticity, and room temperature mechanical properties of Ti-4%Al-1%V-3%Mo alloys modified with 0.01-2 wt.% boron were investigated. Increasing the boron content from 0 to 0.1 wt.% effectively refined prior β-grains, reducing a mean grain size from ~700 µm to ~210 µm. Whiskers of the TiB phase with a size in a range of 0.7-2.9 µm were observed after solidification and thermomechanical processing. Alloys with 0.01-0.1 wt.% boron exhibited similar superplastic elongations and strain rate sensitivity coefficient m of 0.4-0.5 at a strain rate of 1×10-3 s-1 and the elongation to failure decreased from 1000% at 875°С to 400-500% at 700°С. Along with this, the minor boron addition effectively decreased flow stress values, especially at 775 °C, that was explained by the acceleration of the recrystallization and globularization of the microstructure at the initial stage of deformation. Recrystallization-induced decrease in yield strength from 770 MPa to 680 MPa was observed with an increase in boron content from 0 to 0.1 wt.%. Heat treatment increased post-forming strength characteristics for the alloys with 0.01-0.1 wt.% boron by 90–140 MPa without ductility reduction. Alloys with 1-2 wt.% B demonstrated the opposite behavior. The grain refinement effect was not revealed, and prior β grain sizes were ~670-750 µm after solidification. Thermomechanical processing promoted the fragmentation of boride whiskers and the formation of near-spherical particles with a size of ~1 μm for the alloy with a eutectic concentration of 2 wt.% B. A high fraction of borides, ~5-11%, in the alloys with 1-2 wt.% B deteriorated the superplastic properties and drastically decreased ductility at room temperature. The alloy with 2 wt.% B demonstrated non-superplastic behavior and a low level of mechanical properties, meanwhile, the alloy with 1% boron exhibited high-temperature superplasticity at 875 °C with elongation of ~500%, and yield strength of 830 MPa, ultimate tensile strength of 1020 MPa at a room temperature after 100% of superplastic deformation.

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Section: Discussionmentioning

confidence: 99%

“…Alloying with 0.05-0.2 wt.% B (boron) improves the processing and mechanical properties of titanium-based alloys [6][7][8][9]. Boron is low soluble (up to 0.02 wt.% [10,11]) in titanium and it forms fine particles of the TiB phase [12][13][14].…”

Section: Introductionmentioning

confidence: 99%

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Postnikova¹,

Котов²,

Базлов³

et al. 2023

Preprint

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show abstract

“…Alloying with 0.05–0.2 B (boron, wt.%) improves the processing and mechanical properties of titanium-based alloys [ 6 , 7 , 8 , 9 ]. Boron is low-soluble (up to 0.02 wt.% [ 10 , 11 ]) in titanium and it forms fine particles of the TiB phase [ 12 , 13 , 14 ].…”

Section: Introductionmentioning

confidence: 99%

“…The TiB particles solidify at eutectic transformation and exhibit the elongated shape of “whiskers” [ 15 , 16 ]. Trace addition of boron in titanium and titanium-based alloys provides a strong grain refinement effect during solidification [ 8 , 9 , 17 ]. The grain refinement mechanism is related to the TiB phase solidification [ 18 , 19 , 20 , 21 , 22 ].…”

Section: Introductionmentioning

confidence: 99%

Effect of Boron on the Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

et al. 2023

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The decrease of superplastic forming temperature and improvement of post-forming mechanical properties are important issues for titanium-based alloys. Ultrafine-grained and homogeneous microstructure are required to improve both processing and mechanical properties. This study focuses on the influence of 0.01–2 wt.% B (boron) on the microstructure and properties of Ti-4Al-3Mo-1V (wt.%) alloys. The microstructure evolution, superplasticity, and room temperature mechanical properties of boron-free and boron-modified alloys were investigated using light optical microscopy, scanning electron microscopy, electron backscatter diffraction, X-ray diffraction analysis, and uniaxial tensile tests. A trace addition of 0.01 to 0.1 wt.% B significantly refined prior β-grains and improved superplasticity. Alloys with minor B and B-free alloy exhibited similar superplastic elongations of 400–1000% in a temperature range of 700–875 °C and strain rate sensitivity coefficient m of 0.4–0.5. Along with this, a trace boron addition provided a stable flow and effectively reduced flow stress values, especially at low temperatures, that was explained by the acceleration of the recrystallization and globularization of the microstructure at the initial stage of superplastic deformation. Recrystallization-induced decrease in yield strength from 770 MPa to 680 MPa was observed with an increase in boron content from 0 to 0.1%. Post-forming heat treatment, including quenching and ageing, increased strength characteristics of the alloys with 0.01 and 0.1% boron by 90–140 MPa and insignificantly decreased ductility. Alloys with 1–2% B exhibited an opposite behavior. For the high-boron alloys, the refinement effect of the prior β-grains was not detected. A high fraction of borides of ~5–11% deteriorated the superplastic properties and drastically decreased ductility at room temperature. The alloy with 2% B demonstrated non-superplastic behavior and low level of strength properties; meanwhile, the alloy with 1% B exhibited superplasticity at 875 °C with elongation of ~500%, post-forming yield strength of 830 MPa, and ultimate tensile strength of 1020 MPa at room temperature. The differences between minor boron and high boron influence on the grain structure and properties were discussed and the mechanisms of the boron influence were suggested.

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High-temperature deformation behaviors of Ti–2Al–9.2Mo–2Fe alloy with boron

Chen

Hui

et al. 2017

Rare Met.

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Effect of boron addition on formation of a fine-grained microstructure in commercially pure titanium processed by hot compression

Cited by 17 publications

References 18 publications

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Effect of Boron on the Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

High-temperature deformation behaviors of Ti–2Al–9.2Mo–2Fe alloy with boron

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