The TiAl alloy and ZrB2-SiC ceramic are promising materials used at high temperatures. One route to extend their unique applications under extreme conditions relies on successful brazing them together with proper fillers. In this work, brazing temperature influences on microstructural, mechanical, and fractural properties were systemically studied for brazed joints after brazing the TiAl to the ZrB2-SiC with amorphous CuTiZrNi fillers. An optimized brazing was found at 1183 K for 1200 s, yielding a high shear strength of 187 MPa. The joints were mainly consisted of AlCuTi, Ti2Al, (Ti,Zr)2(Cu,Ni), TiB,TiB2, TiCu Ti5Si3, and TiC phases. Brazing temperature substantially changed joint composites. It is found that lower temperature lead to insufficient reaction and remained filler and higher ones to large stress-induced microcracks. Based on element diffusion, a formation mechanism of brazed joint was also proposed.