Effect of Cellulose Nanofibrils on the Bond Strength of Polyvinyl Acetate and Starch Adhesives for Wood

Jiang, Wendy; Tomppo, Laura; Pakarinen, Timo; Sirviö, Juho Antti; Liimatainen, Henrikki; Haapala, Antti

doi:10.15376/biores.13.2.2283-2292

Cited by 29 publications

(19 citation statements)

References 19 publications

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“…Even a small addition of CNF induced considerable improvements in adhesive properties. [ 270 ] In cotton‐seed protein‐based adhesives, ≈2% CNF gave a 22% improvement in dry adhesive strength. [ 271 ]…”

Section: Nanocellulose‐based Hybrid and Functional Hydrogelsmentioning

confidence: 99%

Nanocellulose: Recent Fundamental Advances and Emerging Biological and Biomimicking Applications

et al. 2020

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In the effort toward sustainable advanced functional materials, nanocelluloses have attracted extensive recent attention. Nanocelluloses range from rod‐like highly crystalline cellulose nanocrystals to longer and more entangled cellulose nanofibers, earlier denoted also as microfibrillated celluloses and bacterial cellulose. In recent years, they have spurred research toward a wide range of applications, ranging from nanocomposites, viscosity modifiers, films, barrier layers, fibers, structural color, gels, aerogels and foams, and energy applications, until filtering membranes, to name a few. Still, nanocelluloses continue to show surprisingly high challenges to master their interactions and tailorability to allow well‐controlled assemblies for functional materials. Rather than trying to review the already extensive nanocellulose literature at large, here selected aspects of the recent progress are the focus. Water interactions, which are central for processing for the functional properties, are discussed first. Then advanced hybrid gels toward (multi)stimuli responses, shape‐memory materials, self‐healing, adhesion and gluing, biological scaffolding, and forensic applications are discussed. Finally, composite fibers are discussed, as well as nanocellulose as a strategy for improvement of photosynthesis‐based chemicals production. In summary, selected perspectives toward new directions for sustainable high‐tech functional materials science based on nanocelluloses are described.

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Section: Nanocellulose‐based Hybrid and Functional Hydrogelsmentioning

confidence: 99%

Nanocellulose: Recent Fundamental Advances and Emerging Biological and Biomimicking Applications

et al. 2020

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“…Nanocellulose have high surface to volume ratio and primary hydroxyl groups which can be modified [44]. In wood adhesives, hence by addition of very small amount of nanocellulose, enhancement of properties is observed [45] [46] [47] [48].…”

Section: Introductionmentioning

confidence: 99%

Chemical Modification of Nanocellulose in Wood Adhesive: Review

Vineeth¹,

Gadhave²,

Gadekar³

2019

OJPChem

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Bio-based nanomaterial is more attractive, due to its abundance, eco-friendliness and sustainability, when compared to the non-renewable toxic petrochemicals used in the wood adhesive sector. Recent studies on the formaldehyde emission by petrochemical binders in wood adhesives have attracted scientists for the research in biomaterial-based binders. In this aspect nanocellulose (NC) is one such material which has reinforcing ability and has natural binding properties. Conventional wood adhesive uses petrochemical-based binders and additives. Inclusion of nanocellulose in wood adhesive could drastically reduce the dependency on non-renewable petroleum sources. Even though wood adhesive uses NC for improving mechanical properties of the adhesive, usage is restricted because of its inability to enhance tackiness and adhesion compared with petrochemicals. Availability of free hydroxyl groups and feasibility for modification can be a potential way for functionalization of this nanomaterial. To improve adhesion properties and to make nanocellulose act as a functional filler, the crosslinking approach can be a possible solution. Enhancement of thermal properties with improved thermal degradation, water barrier properties of crosslinked films and enhanced mechanical properties especially in crosslinked poly (vinyl alcohol) (PVA) matrix, which is one of the binders for wood adhesive discussed in this review paper proves the potential applicability of crosslinked NC. Hence by inclusion of NC in wood adhesive and crosslinking with the binder, both mechanical and performance properties are expected to enhance which will create a new world and possibilities for the bio-based eco-friendly wood adhesives. In this review paper, we have reviewed the crosslinking of nanocellulose to enhance the performance of wood adhesives.

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“…Trunks with a length of 1.5 m were cut and from each trunk, sample logs of 40 cm length were taken in order to cut boards in radial direction with 2 cm thickness and 8 cm width. The boards were then cut in fiber direction and sanded to a final thickness of 5 mm, followed by conditioning in standard climate (temperature: 20 ± 2 • C, relative humidity: 65 ± 5%) to reach an equilibrium moisture content of about 12% according to [35].…”

Section: Wood Materialsmentioning

confidence: 99%

Impact of Bio-Based (Tannins) and Nano-Scale (CNC) Additives on Bonding Properties of Synthetic Adhesives (PVAc and MUF) Using Chestnut Wood from Young Coppice Stands

Marini

Zikeli

Corona³

et al. 2020

Nanomaterials

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Sustainability and ecotoxicity issues call for innovations regarding eco-friendly adhesives in the production of biocomposite wood materials, and solutions involving nano-scale and bio-based compounds represent a valid and promising target. One possible approach is to increase the performance of adhesives such as polyvinyl acetate (PVAc) or melamine-urea-formaldehyde (MUF) by means of nanoparticles in order to obtain a material with better mechanical and environmental resistance. When applying cellulose-based nanoparticles or tannin, the concept of a circular economy is successfully implemented into the forest/wood value chain, and chances are created to develop new value chains using byproducts of forestry operations. In this study, assortments coming from young sweet chestnut (Castanea sativa Mill.) coppice stands were utilized for the preparation of single lap joint assemblies using different commercial adhesives (PVAc, MUF) and cellulose nanocrystals (CNC) and tannin as additives. The results showed that addition of CNC and tannin to PVAc glue increased tensile shear strength in lap joint tests presenting a promising base for future tests regarding the addition of CNC and tannin in MUF or PVAc adhesive formulations. Unfortunately, the tested bio-based additives did not reveal the same encouraging results when tested in the wet state.

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Effect of Cellulose Nanofibrils on the Bond Strength of Polyvinyl Acetate and Starch Adhesives for Wood

Cited by 29 publications

References 19 publications

Nanocellulose: Recent Fundamental Advances and Emerging Biological and Biomimicking Applications

Nanocellulose: Recent Fundamental Advances and Emerging Biological and Biomimicking Applications

Chemical Modification of Nanocellulose in Wood Adhesive: Review

Impact of Bio-Based (Tannins) and Nano-Scale (CNC) Additives on Bonding Properties of Synthetic Adhesives (PVAc and MUF) Using Chestnut Wood from Young Coppice Stands

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