Colloidal silica (CS) is a kind of nanomaterial used in soil/rock grouting techniques in different branches of civil engineering. Many studies have recently been performed to investigate the potential of CS in improving the mechanical behavior of cohesionless soils and mitigating the risk of seismic liquefaction in urbanized areas. CS grout is chemically and biologically inert and, when injected into a subsoil, it can form a silica gel and stabilize the desired soil layer, thus representing an attractive, environmentally friendly alternative to standard chemical grouting techniques. This paper firstly describes the characteristics of CS grout, the gelation process and the main features of the behavior of the pure gelled material. The grout delivery mechanisms through porous media are then explained, pointing out the crucial issues for practical application of CS grouting. All the grouting-induced effects on the soil behavior, which have been investigated by laboratory tests on small-sized soil elements, are reviewed, including the modifications to soil strength and stiffness under both static and seismic loading conditions, to soil compressibility and hydraulic conductivity. Published results from physical model tests and in situ applications are also presented. Finally, some aspects related to the mechanism of soil improvement are discussed. A critical discussion of each topic is presented, drawing particular attention to the controversial or not yet fully examined aspects to which future research on colloidal silica grouting should be directed.