“…Lu et al [23] found that montmorillonite has a pronounced catalytic effect on the release of biomarkers in the 2-10 h pyrolysis at 200°C and on the rate of isomerization and degradation at 300°C pyrolysis. Al-Harahsheh et al [27] studied the effect of demineralization on oil yield and found that removal of carbonate by HCl reduced the oil to gas ratio, whereas, this ratio increased after HF treatment. Skala et al [14] and Abuolkas and El Harfi [24] reported that the activation energy and frequency factor of kerogen concentrate prepared by acid demineralization are lower than that of raw oil shale.…”