Effect of different catalysts on the cracking of Jatropha oil

Biswas, Shelly; Sharma, D. K.

doi:10.1016/j.jaap.2014.10.001

Cited by 32 publications

(17 citation statements)

References 25 publications

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“…3a). Such decrease in light fractions also occurs in the catalytic cracking of jatropha oil by zeolite ZSM-5 and ZSM SiAl 36) , which resembled our present study in the presence of matrix. The gasoline fraction (C5 to C11) increased from 51 to 62 % maximum using zeolite-containing catalysts.…”

Section: Catalytic Cracking Of Soybean Oil Usingsupporting

confidence: 90%

Catalytic Cracking of Soybean Oil Using Zeolite-containing Microporous and Mesoporous Mixed Catalysts with Curie Point Pyrolyzer

Sontisawate

Nasu

Hashimoto

et al. 2016

J. Jpn. Petrol. Inst.

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Zeolite-containing catalysts with hierarchical structures were prepared by combining microporous zeolites (beta and Y zeolite) with mesoporous matrices (silicas and silica _ aluminas with large mesopores) prepared by the gel skeletal reinforcement method and a binder. Morphology of the prepared catalysts was characterized by X-ray diffraction, nitrogen adsorption-desorption, ammonia adsorption-desorption, and thermogravimetric-differential thermal analysis. Catalytic cracking of soybean oil was performed with these mixed catalysts to observe the effect of the pore size on the catalytic activity and the selectivity of products using the convenient Curie point pyrolyzer. Zeolite-containing mixed catalysts exhibited great improvements in all aspects such as maximum increase of 31 % conversion, about 10 % higher gasoline yields, and maximum decrease of 36 % coke formation in comparison with single zeolite, indicating that the presence of the matrices greatly influenced the catalytic cracking. The yields of gasoline, single branched and multi-branched hydrocarbons increased with higher conversion, indicating that increased conversion was necessary to obtain higher yields of products. In comparison of product yields at the same conversion, Y zeolite-containing catalysts exhibited the higher yields than beta (β) zeolite-containing catalysts, indicating that the larger micropore diameter of Y zeolite in the catalysts induced the increase in the gasoline fraction and promoted the isomerization to produce the bulkier products. The conversion of soybean oil increased with increasing the pore diameter for β series catalysts and the conversions were maximum for MAT (

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Section: Catalytic Cracking Of Soybean Oil Usingsupporting

confidence: 90%

Catalytic Cracking of Soybean Oil Using Zeolite-containing Microporous and Mesoporous Mixed Catalysts with Curie Point Pyrolyzer

Sontisawate

Nasu

Hashimoto

et al. 2016

J. Jpn. Petrol. Inst.

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show abstract

“…The bio-oil yield decreased while the syngas yield increased over Zn/ZSM-5 catalyst compared to the non-catalytic pyrolysis trials. Biswas and Sharma [8] studied the effect of different catalysts including ZSM-5, ZSM-5 + SiAl and NiMo/SiAl on the cracking of jatropha oil. The ZSM-5 + SiAl catalyst was found the best one for the cracking of jatropha oil at 375°C, forming 36% gasoline range hydrocarbons (C 7 -C 11 ) and 58% diesel range hydrocarbons (C 12 -C 22 ) in the liquid product.…”

Section: Introductionmentioning

confidence: 99%

Catalytic cracking of camelina oil for hydrocarbon biofuel over ZSM-5-Zn catalyst

Zhao

Wei

Cheng

et al. 2015

Fuel Processing Technology

108

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“…In general, microvolume of ZSM-5 was impregnated by Ni decreased compared to pure ZSM-5. These results may indicate that Ni particles partially block the microchannels of ZSM-5 and reduces the accessibility of the micropores [13]. In addition, the mesoporous volume of the Ni/ZSM-5 increases at first and then decreases with increasing Ni loading.…”

Section: Product Analysismentioning

confidence: 92%

“…For example, Ni/ZSM-5 catalysts which have been widely used for the reaction of hydrogenation, isomerization, dehydrogenation, oxidation, aromatization, production of hydrogen, carbon nanotube preparation, reduction of NOx and hydrocracking. Several methods can be used in the manufacture of nickel-containing catalysts include precipitation, impregnation and ion exchange processes, chemical vapor deposition, mechanical mixing compounds containing nickel and support, solid state reaction, the introduction of nickel precursors for the synthesis support [12,13].…”

Section: Introductionmentioning

confidence: 99%

Effect of modification ZSM-5 catalyst in upgrading quality of organic liquid product derived from catalytic cracking of Indonesian nyamplung oil (Calophyllum inophyllum)

Dewajani¹,

Rochmadi²,

Purwono³

et al. 2016

AIP Conference Proceedings

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Effect of different catalysts on the cracking of Jatropha oil

Cited by 32 publications

References 25 publications

Catalytic Cracking of Soybean Oil Using Zeolite-containing Microporous and Mesoporous Mixed Catalysts with Curie Point Pyrolyzer

Catalytic Cracking of Soybean Oil Using Zeolite-containing Microporous and Mesoporous Mixed Catalysts with Curie Point Pyrolyzer

Catalytic cracking of camelina oil for hydrocarbon biofuel over ZSM-5-Zn catalyst

Effect of modification ZSM-5 catalyst in upgrading quality of organic liquid product derived from catalytic cracking of Indonesian nyamplung oil (Calophyllum inophyllum)

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