Conductive polymer composites require a threedimensional 3D network to impart electrical
conductivity. A general method that is applicable to most polymers for achieving a desirable
graphene 3D network is still a challenge. We have developed a facile technique to fabricate
highly electrical conductive composite using vacuumassisted infusion of epoxy into graphene
sponge GS scaffold. Macroscopic GSs were synthesized from graphene oxide solution by a
hydrothermal method combined with freeze drying. The GSepoxy composites prepared display
consistent isotropic electrical conductivity around 1Sm, and it is found to be close to that
of the pristine GS. Compared with neat epoxy, GSepoxy has a 12ordersofmagnitude increase in
electrical conductivity, attributed to the compactly interconnected graphene network
constructed in the polymer matrix. This method can be extended to other materials to
fabricate highly conductive composites for practical applications such as electronic
devices, sensors, actuators, and electromagnetic shielding.