2001
DOI: 10.1016/s0926-860x(01)00641-x
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Effect of metal composition on hydrogen selectivity in steam reforming of methanol over catalysts prepared from amorphous alloys

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Cited by 46 publications
(32 citation statements)
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“…There are two main catalyst systems for steam reforming of methanol; one is supported copper catalyst group [16][17][18][19][20][21][22][23] and the other is supported palladium catalyst group [24]. Two causes of deactivation of the supported copper catalysts are proposed: coking of the catalysts [16] and change of the oxidation state of copper [17].…”
Section: Introductionmentioning
confidence: 99%
“…There are two main catalyst systems for steam reforming of methanol; one is supported copper catalyst group [16][17][18][19][20][21][22][23] and the other is supported palladium catalyst group [24]. Two causes of deactivation of the supported copper catalysts are proposed: coking of the catalysts [16] and change of the oxidation state of copper [17].…”
Section: Introductionmentioning
confidence: 99%
“…The reason of this trend is probably due to carbon deposition during long-term experiments. In fact, carbon deposition is the main problem of methanol steam reforming carried out over Cu-containing catalysts [3]. Moreover, long-term (20 h) experiments carried out using the TR gave an amount of 0.117 g of carbon deposited on the catalyst surface.…”
Section: Resultsmentioning
confidence: 99%
“…The methanol steam reforming (MSR) reaction is viewed as a very interesting and promising method for hydrogen production useful for fuel cell applications [1][2][3][4]. According to the literature, the chemical reactions considered are as follows: Reactions (1) and (3) are both reversible and endothermic reactions and proceed under volume increase, suggesting that the highest methanol conversions are obtained at high temperature and low pressure.…”
Section: Introductionmentioning
confidence: 99%
“…The methanol steam reforming reaction is viewed as a very interesting, promising method for hydrogen production useful for fuel cell applications [70,[94][95][96]. According to the literature, the chemical reactions considered are the following:…”
Section: Methanol Steam Reformingmentioning
confidence: 99%