The kinetics of the methanation of carbon dioxide was investigated using an alumina supported Ni‐La2O2 catalyst in a differential and integral reactor. In the differential reactor the molar ratio of H2 to CO2 was varied from 0.6 to 30. In the integral reactor the rates were measured with up to 90% conversion. Both reactor tests were carried out at temperatures between 513 and 593 K. The experimental results were described by a Langmuir‐Hinshelwood type equation. The kinetics can be explained by assuming equilibrium of dissociative carbon dioxide and hydrogen adsorption, and assuming hydrogenation of surface carbon as the rate determining step.
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