This
work presents a numerical analysis of spray combustion and
associated emissions formation for methyl esters of soybean (SME)
and coconut (CME) in a constant volume bomb and a light-duty diesel
engine. SME and CME were used to represent biodiesel fuels with high
and low unsaturation levels, respectively. In the constant volume
bomb, diesel engine-like conditions were used, where two ambient oxygen
(O2) levels of 15% and 21% (by mole fraction) were specified
to study the effects of exhaust gas recirculation on the combustion
and soot formation of biodiesel fuels. As the ambient O2 level increased to 21%, the lift-off length (LOL) was reduced by
25%, while the maximum soot volume fraction (SVF) at quasi-steady
state was 4 times higher. The effects of unsaturation levels were
next investigated under 21% ambient O2 level. When the
unsaturation level was increased, the ignition delay (ID) periods
and LOL did not vary significantly as a relative difference of less
than 10% was observed between both. A higher local equivalence ratio
(φ) and hence maximum SVF were observed in the SME combustion.
A higher adiabatic flame temperature (T) of approximately
40 K was also recorded in the SME test case. Additionally, higher
soot formation and oxidation rates were found for SME. In the diesel
engine cases at 21% ambient O2 level, the φ–T distributions and in-cylinder peak pressures predicted for SME and
CME were identical. Meanwhile, the peak soot formation rate predicted
for SME was increased by 7% as compared to that of CME. Similarly,
the peak soot oxidation due to O2 calculated for SME was
30% higher than that of CME, while the oxidation rates due to hydroxyl
(OH) were similar for both fuels. For the tested conditions, the rates
of production of acetylene (C2H2) and nitrogen
oxides (NO
x
) were increased by 43% and
12%, respectively, as a result of the increase in unsaturation level.