2007
DOI: 10.1016/j.polymer.2007.09.020
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Effect of nucleation and plasticization on the crystallization of poly(lactic acid)

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Cited by 711 publications
(597 citation statements)
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“…The decrease in Tg is a clear evidence of the plasticization effect. OES plasticizers allows chain mobility due to the free volume and reduced chain interactions [39]. In good agreement with previously described DMTA behavior, DSC shows a clear decrease in Tg with OES plasticizer.…”
Section: Figuresupporting
confidence: 90%
“…The decrease in Tg is a clear evidence of the plasticization effect. OES plasticizers allows chain mobility due to the free volume and reduced chain interactions [39]. In good agreement with previously described DMTA behavior, DSC shows a clear decrease in Tg with OES plasticizer.…”
Section: Figuresupporting
confidence: 90%
“…All films (30 × 7 × 0.5 mm 3 ) were tested at a strain of 0.01% using a 3 °C min -1 , temperature ramp from -50 to 120 °C.…”
Section: Dynamic Mechanical Analysis (Dma)mentioning
confidence: 99%
“…PLA like most synthetic polymers from petroleum resources, which are rarely used alone by themselves, and needs to improve some properties by an inclusion of additives [2] . Poly (lactic acid) PLA has very low toxicity and high mechanical performance, comparable to other commercial polymers, for example, poly (ethylene terephthalate) (PET) and polystyrene (PS) [3][4][5] . It is highly transparent and has good barrier properties to aromas.…”
Section: Introductionmentioning
confidence: 99%
“…These grades have different D-lactic monomer contents, 4.25 and 2% respectively [17][18][19][20], and weight average molecular weights, 212 and 207 kDa respectively, assessed by Gel Permeation Chromatography (GPC) [21]. Sheets with both materials were obtained by cast sheet extrusion in a single-screw COLLIN Teach-Line ® E16T extruder (T = 145-200°C, 50 rpm).…”
Section: Experimental Part 21 Materials and Processingmentioning
confidence: 99%