Effect of OH-content on thermal and chemical properties of SnOP2O5 glasses

Ehrt, D.

doi:10.1016/j.jnoncrysol.2007.07.092

Cited by 43 publications

(31 citation statements)

References 6 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Table 1 summarizes the glass trassition temperature Tg, density ρ, moral volume, refractive index nD at 589 nm and Abbe number vD of xSnO -(100-x) P2O5 glasses where x = 52, 57, 62, 67 and 72 mol%. The data of glass trassition temperature, 1),2),13), 14) density 1), 14) and refractive index 1), 14) show similar tendencies with values reported previously. Figure 1 shows the variation of nD with SnO concentration.…”

Section: Resultssupporting

confidence: 89%

Compositional dependence of properties of SnO-P2O5 glasses

Cha

Kubo

Takebe

et al. 2008

J. Ceram. Soc. Japan

View full text Add to dashboard Cite

Binary SnO-P2O5 (SP) glasses with 52-72 SnO mol% were examined. Glass transition temperature, density, refractive index and absorption edge were studied for transparent SP glasses. The structure of SP glasses was evaluated by FT/IR and Raman spectroscopy. The water durability was investigated by weight loss and Raman spectroscopy for SP glass samples immersed in distilled water at 30-70°C. Raman spectra indicated in the immersion test that Q 1 units form and Q 2 units decrease as a result of water attack upon the phosphate chains with increasing immersion time in 62SnO·38P2O5 glass and no structural change was observed in 72SnO·28P2O5 glass. The relationship between the properties and glass structure with chemical bonding is discussed.

show abstract

Section: Resultssupporting

confidence: 89%

Compositional dependence of properties of SnO-P2O5 glasses

Cha

Kubo

Takebe

et al. 2008

J. Ceram. Soc. Japan

View full text Add to dashboard Cite

show abstract

“…Earlier Mossbauer studies on certain phosphate composites and amorphous materials containing tin oxide have revealed that the Sn ions do exist in both Sn 2+ and Sn 4+ states [17,24]. The Sn 2+ ion possesses an electron lone pair and forms the Fig.…”

Section: Discussionmentioning

confidence: 99%

Influence of tin ions on AC conductivity and dielectric features of Li2O–PbO–P2O5 glass system

Puli

Almeida

Gandhi³

et al. 2015

Ionics

View full text Add to dashboard Cite

Li 2 O-PbO-P 2 O 5 glasses mixed with different concentrations of SnO 2 (ranging from 0 to 7.0 mol%) were prepared. AC conductivity (σ ac ) and dielectric dispersion have been studied. The results were analyzed on the basis of space charge and orientation polarization models. σ ac exhibited the maximal effect, whereas the activation energy for the conductivity demonstrated minimum at 3.0 mol% of SnO 2 . In the low-temperature region, σ ac is nearly temperatureindependent and is varied linearly with frequency. Such behavior is explained based on quantum mechanical tunneling (QMT) model. These results additionally confirm that there is both ionic and electronic originated conductivity in these glasses. The quantitative analysis of these results with the aid of data on optical absorption and IR spectral studies indicated that the network of the glass mixed with 3.0 mol% of SnO 2 possessed higher degree of disorder and exhibited maximum conductivity.

show abstract

“…4). Ehrt 7) reported that tin phosphate glass samples are able to incorporate water in their glass structure depending on their melting temperature with remarkable effects on thermal and chemical properties. The increase of the OH content in the glass brings the increase of weak sites in the glass network, therefore A-SP glasses have higher Tg values than that of C-SP glasses (Fig.…”

Section: Discussionmentioning

confidence: 99%

“…The compositional dependence of aluimina in phosphate glasses has been reviewed by Kirkpatrick and Brow 5) The alumina dissolution from crucible by Hussin et al 6) was studied. 6) Ehrt 7) reported the effect of OH content in tin phosphate glasses depending on the melting temperature.…”

Section: Introductionmentioning

confidence: 99%

Compositional dependence of photoelasticity of tin phosphate glasses

Cha

Kawano

Takebe

et al. 2008

J. Ceram. Soc. Japan

View full text Add to dashboard Cite

The photoelastic constants (PECs) of transparent SnO-P2O5 (SP) glasses with 52-72 mol% SnO were determined using a frequency stabilized transverse Zeeman He-Ne laser (STZL) at 633 nm. The SP glass samples were melted at 950°C in carbon crucibles and at 1050°C in alumina crucibles. The melting conditions affect the values of glass transition temperature and OH content but have almost no effect on PEC. The PEC varies monotonically with increasing SnO concentration from -0.73 to -1.98 × 10 -12 Pa -1 .

show abstract

Effect of OH-content on thermal and chemical properties of SnOP2O5 glasses

Cited by 43 publications

References 6 publications

Compositional dependence of properties of SnO-P2O5 glasses

Compositional dependence of properties of SnO-P2O5 glasses

Influence of tin ions on AC conductivity and dielectric features of Li2O–PbO–P2O5 glass system

Compositional dependence of photoelasticity of tin phosphate glasses

Contact Info

Product

Resources

About