Effect of P on hydrodeoxygenation performance of Ni–P/SiO₂ catalysts for upgrading of m-cresol

Abstract

To deeply understand the role of P in Hydrodeoxygenation (HDO), the SiO2-supported Ni and Ni-P catalysts with different P/Ni ratios (x) were prepared. The as-prepared samples were characterized by various...

Carbon-coated nickel phosphide with enriched surface Niδ+ sites enables an exceptionally high productivity of 2-methylfuran from biomass upgrading

“…These surface-enriched Ni δ+ species suggests its potential hydrodeoxygenation activity. [54][55][56]…”

Recent Advances for Chiral Sulfoxides in Asymmetric Catalysis

“…In 2018, Zhang and co-workers synthesized chiral O,P-ligands for the Pd-catalyzed enantioselective arylation of general sulfenate anions (Scheme 43 ). 65 The chiral O,P-ligands were easily prepared from inexpensive commercial raw materials. The single crystal structure of ligand/PdCl 2 suggested the formation of a rarely observed 11-membered ring with the O,P-coordination center of Pd(II).…”